M. Gerloch,
R. C. Slade
Ligand-Field Parameters
Paperback Engels 2009 9780521105668Levertijd ongeveer 9 werkdagen
Gratis verzonden
Samenvatting
This volume was originally published in 1973. The nature of the non-symmetry determined aspects of ligand-field theory receives inadequate treatment in most texts. This book is concerned with the nature of the ligand-field parameters used to describe the electronic properties of transition metal complexes having cubic and lower symmetries. These radial parameters constitute the non-symmetry-determined part of ligand-field theory. Symmetry-based properties are discussed here only to emphasize the separate roles of splitting factors and symmetry. The reader is assumed to be familiar with the usual approach to ligand-field theory and with elementary group theory.
Specificaties
ISBN13:9780521105668
Taal:Engels
Bindwijze:Paperback
Aantal pagina's:248
Uitgever:Cambridge University Press
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Inhoudsopgave
1. Symmetry versus splitting parameters; 2. The crystal-field formalism; 3. Interelectron repulsion parameters; 4. Radical parameters for angularly-distorted systems; 5. Radical parametres for quadrate symmetry; 6. The nature and calculation of 10Dq; 7. A crystal-field approach to radical parameters; 8. Semi-empirical molecular-orbital approaches; 9. The Nephelauxetic effect.
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