Dipolar Correlation Spectroscopy

Higher-Order Correlation Terms in Three-Spin Double Electron-Electron Resonance (DEER)

Paperback Engels 2015 9783658091903
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Samenvatting

Bettina Basel presents experimental conditions which allow to extract the three-spin contribution precisely from experimental multi-spin double electron-electron resonance (DEER) signals. The theory and concepts behind the used techniques, which are among others broadband chirp pump pulses, over coupling of microwave resonators and echo reduction measurements, are discussed and explained in detail. Moreover the setup and results of DEER experiments with newly introduced double chirp pump pulses consisting of two separate chirps are shown. Particular attention is paid to the phenomenon of orientation selection and the concept of orthogonal spin labeling.

Specificaties

ISBN13:9783658091903
Taal:Engels
Bindwijze:paperback
Aantal pagina's:148
Uitgever:Springer Fachmedien Wiesbaden

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Inhoudsopgave

DEER with Chirp and Double Chirp Pump Pulses.- Coupling of the Resonator and Determination of Its Resonance Profiles.- Gd(III)-Nitroxide DEER.- Echo Reduction Measurements.

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        Dipolar Correlation Spectroscopy