Aromatic C-nitroso Compounds

Name: Aromatic C-nitroso Compounds
Author: Hrvoj Vančik

Paperback Engels 2015 9789401780643

180,99

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This book is designed to collect and review the research covering main directions in investigations of aromatic nitroso compounds in last decades, and to present both, the academic aspects of this chemistry, as well as the open field of its applicability. The book is divided in five chapters. The basic structural properties of the nitroso aromatic molecules are described in the first chapter. The second chapter is an overview of the methods of preparations of aromatic nitroso and polynitroso compounds, including classical synthetic methods and some new preparative approaches. The third part deals with the physico-chemical properties of nitroso aromates and azodioxides, its structure, crystallography, quantum chemical calculations, spectroscopy, typical reactions, and especially it is focused on the dimerizations in the solid-state. In the fourth chapter is represented organometallic chemistry of nitroso aromatic molecules and its applications in catalysis. The last part of the book deals with the behavior of this class of compounds in the biological systems, reactions with biomolecules and the use in toxicology.

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ISBN13:9789401780643

Taal:Engels

Bindwijze:paperback

Uitgever:Springer Netherlands

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Introduction: Aliphatic and aromatic nitroso compounds1. Molecular structures 1.1 Calculated molecular structures 1.2 Experimental geometries2. An overview of synthetic methods for preparation of nitrosoaromatic compounds 2.1 Reductive methods 2.2 Oxidative methods 2.3 Solid-state syntheses 2.4 Enzyme catalyzed oxidations 2.5 Direct nitrosation 2.6 Heteroaromatic compounds 2.7 Nitrosoaromatic compounds with more nitroso groups 2.8 Synthesis of azoxides and azodioxides3. Molecular properties and spectroscopy 3. 1 Physical Organic Chemistry 3.1.1 Nature of the NO group. 3.1.2 Nucleophilic properties 3.1.3 Reactions with nucleophiles 3.1.3.1 Oxygen as nucleophile 3.1.3.2 Sulfur as nucleophile 3.1.3.3 Carbon as nucleophile 3.1.3.4 Nitrogen as nucleophile 3.1.4 Superacid medium 3.1.5 Nitroso cycloadditions 3.1.5.1 Stepwise cycloadditions 3.2 Dimerizations and Spectroscopy 3.2.1 NMR spectroscopy 3.2.1.1 1HNMR 3.2.1.2 Multinuclear NMR 3.2.1.3 13C NMR 3.2.1.4 14N NQR 3.2.1.5 15N NMR spectra 3.2.1.6 17O NMR 3.2.2 UV-VIS spectroscopy 3.2.3 Photoelectron spectroscopy 3.3 Monomer-dimer equilibrium 3.3.1 Dimerizations and polymerizations of dinitroso compounds 3.3.2 Vibrational spectroscopy 3.3.3 Kinetics of dimerisation in solid-state 3.3.4 Cross dimerizations 3.3.5 Dimerizations of heteroaromatic derivatives 3.3.6 Calculations of the reaction path 3.4 Electrochemistry 3.4.1 Aromatic nitroso compounds as spin traps 3.5 Photochemistry 3.5.1 Photoreactions including nitrosoaromatic intermediates4. Organometallic compounds 4.1 Structures and properties of nitrosoaromatic-metal complexes 4.2 Nitrosoaromatic-heme complexes5. Bilological systems 5.1 Reactions with fatty acids and steroides 5.2 Reactions with thiol consisting biomolecules 5.3 Redox reactions and nitrosoaryl compounds in biological systemsReferencesSUBJECT INDEX

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